Ultrathin, stretchable, and 3D-printable nanotube composites can defend electronics from each electromagnetic interference (EMI) and neutron radiation in excessive environments.
Research: Ultrathin, Stretchable, and 3D-Printable Complementary Nanotubes–Polymer Composites for Multimodal Radiation Shielding in Excessive Environments. Picture Credit score: Wanut Sawangwong/Shutterstock.com
In a examine printed in Superior Supplies, researchers mixed single-walled carbon nanotubes (SWCNTs) with boron nitride nanotubes (BNNTs) to create a light-weight shielding system with two complementary roles: SWCNTs suppress electromagnetic interference, whereas BNNTs soak up neutrons.
The staff first demonstrated the idea in ultrathin hybrid nanotube movies, then prolonged it right into a stretchable, 3D-printable polymer composite. The work factors to a promising route for shielding supplies in aerospace, nuclear, medical, and protection applied sciences, the place standard safety is commonly too heavy or inflexible.
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Digital methods working in house, nuclear amenities, medical radiation settings, and protection environments face two persistent threats: electromagnetic interference and high-energy neutron radiation. Each can disrupt or injury delicate elements, decreasing reliability in situations the place failure could also be expensive or harmful.
Conventional shielding supplies, together with metals and concrete, can present efficient safety, however they’re heavy, rigid, and poorly suited to light-weight or deformable electronics. That has change into a rising downside as gadgets change into smaller, lighter, and extra adaptable, significantly in versatile electronics and wearable methods.
Two Nanotubes, Two Jobs
The fabric system is constructed round two nanotube sorts with completely different strengths. SWCNTs are electrically conductive and efficient at attenuating electromagnetic waves. BNNTs, in the meantime, include boron atoms with a excessive neutron absorption cross-section, making them well-suited to neutron shielding.
Earlier research had largely examined these supplies individually. Right here, the researchers mixed them right into a single multifunctional system designed to handle each challenges without delay.
Creating the Materials
The staff first dispersed SWCNTs and BNNTs in resolution utilizing surfactants to supply secure suspensions and uniform mixing. Free-standing hybrid movies have been then made by vacuum filtration, yielding constructions usually 10 to twenty µm thick.
Microscopy confirmed a coaxial structure by which SWCNT bundles wrapped round BNNT cores. Raman spectroscopy and Fourier-transform infrared spectroscopy indicated pressure interactions between the 2 nanotube methods, whereas elemental mapping confirmed the distribution of boron, nitrogen and carbon all through the hybrid construction.
To make printable composites, the researchers then integrated the nanotube community right into a polydimethylsiloxane (PDMS) elastomer matrix. The ensuing ink was processed by direct ink writing, an extrusion-based 3D-printing methodology that allows layer-by-layer fabrication of complicated geometries. Rheological testing confirmed that the ink had the viscoelastic properties wanted for printing.
Additional measurements, together with conductivity assessments, thermogravimetric evaluation, and neutron attenuation experiments, have been used to judge electrical, thermal, and mechanical efficiency.
Research Outcomes
The hybrid nanotube movies fashioned a dense, interconnected community with robust interfacial contact and steady conductive pathways. That construction supported cost transport and underpinned the fabric’s electromagnetic shielding efficiency.
Within the X-band frequency vary, the neat hybrid movies achieved EMI shielding effectiveness above 50 dB at micrometer-scale thicknesses. The shielding was primarily absorption-dominated reasonably than reflection-dominated: power was dissipated primarily via ohmic losses in conductive SWCNT pathways, with interfacial polarization enjoying a secondary function.
The examine additionally discovered that percolated SWCNT networks persevered throughout a variety of compositions, serving to protect EMI shielding even when BNNT content material was excessive.
For neutron shielding, a composite with an SWCNT:BNNT ratio of two:8 achieved a neutron attenuation coefficient of about 1.27 mm-1, similar to roughly 72 % attenuation at a thickness of 1 mm. That efficiency was pushed primarily by boron atoms within the BNNT construction.
Skinny Movies and Printable Composites
When the nanotube community was embedded in PDMS, the fabric turned stretchable and printable whereas retaining helpful shielding efficiency. Mechanical assessments confirmed fracture strains above 125 %, and EMI shielding remained secure via repeated deformation cycles. Thermal testing confirmed structural stability from cryogenic temperatures close to −196 °C to elevated temperatures round 250 °C.
On this polymer-composite kind, EMI shielding effectiveness reached as much as about 23 dB at sub-millimeter thicknesses. That’s decrease than the efficiency reported for the neat nanotube movies, however nonetheless important for versatile functions the place printability and mechanical compliance matter.
Structure Additionally Adjustments Efficiency
The examine suggests shielding relies upon not solely on composition but in addition construction. Utilizing direct ink writing, the staff produced geometrically tunable designs, together with honeycomb lattices. These architectures elevated electromagnetic attenuation by selling a number of inside reflections.
The authors current this as an encouraging early consequence reasonably than a remaining optimisation, however it exhibits how additive manufacturing might be used to tune shielding efficiency via geometry in addition to materials chemistry.
The Larger Image
Taken collectively, the findings define a sensible technique for multifunctional shielding in harsh environments. The neat hybrid movies delivered the strongest mixed EMI and neutron shielding, whereas the 3D-printable PDMS composites supplied a extra versatile and application-oriented model of the identical idea.
The broader significance lies in combining low weight, mechanical sturdiness, thermal resilience, and twin shielding in a single platform. That might make the strategy helpful for future digital methods that want dependable safety in demanding working situations.
Journal Reference
Flandy, Kim, Okay., et al. (2026). Ultrathin, Stretchable, and 3D-Printable Nanotubes-Polymer Composites for Multimodal Radiation Shielding in Excessive Environments. Superior Supplies, e13805. DOI: 10.1002/adma.202513805
