Researchers on the Vienna College of Know-how (TU Wien) have developed a 3D printing course of that enables hidden codes and symbols to be constructed instantly into printed supplies. The brand new technique offers scientists management over the construction and properties of the fabric at each level, enabling objects that may change look relying on temperature.
Revealed in Nature Communications, the advance removes one of many key limitations of conventional 3D printing, which often depends on a single materials with uniform properties. By adjusting how gentle interacts with liquid substances throughout printing, the TU Wien staff can differ the hardness, transparency, and elasticity of the fabric.
“We will use totally different gentle intensities, totally different wavelengths, or totally different temperatures,” says Katharina Ehrmann from Institute of Utilized Artificial Chemistry. “All of this can be utilized to affect the properties of the 3D-printed materials.”


Controlling Materials Properties with Gentle
For this examine, the researchers labored with liquid supplies that solidify when uncovered to gentle. The place the sunshine strikes, a chemical response hyperlinks the molecular constructing blocks collectively, turning the liquid right into a strong. By fastidiously adjusting the sunshine’s depth, wavelength, and temperature, the researchers can management how the molecules manage themselves — forming both an orderly crystalline construction or a extra random, amorphous one.
“Relying on the crystallinity, the fabric properties may also differ tremendously,” explains Researcher Michael Göschl, first writer of the examine. “Crystalline supplies are typically onerous and brittle, whereas amorphous supplies can typically be mushy and elastic. The optical properties may also differ, from glass-like transparency to opaque white,” provides Researcher Dominik Laa.

Demonstrating Sensible Purposes
The staff demonstrated the flexibleness of their technique with a number of examples. In a single, they produced a plastic object containing an invisible QR code hidden beneath a crystalline layer. When heated to a particular temperature, the crystalline layer turns into clear and the QR code is revealed. As the fabric cools, the layer returns to its unique state, as soon as once more hiding the code.
The identical precept was used to print a warning image that seems solely when the temperature rises past a sure restrict, providing a doable device for monitoring heat-sensitive items. Optical characterization of the supplies was carried out in collaboration with Professor Andrei Pimenov’s analysis group at TU Wien’s Institute of Stable State Physics.
“We’re providing a very new vary of potentialities for 3D printing,” says Ehrmann. “Potential purposes could be envisaged in many alternative areas, from knowledge storage and safety to biomedical purposes.”
Gentle-Based mostly Strategies in 3D Printing
TU Wien’s method is a part of a broader development in light-based 3D printing strategies that goal to boost materials management and enhance printing precision.
As an illustration, Massachusetts Institute of Know-how (MIT) researchers not too long ago developed a 3D printing technique that makes use of a light-sensitive resin able to forming each sturdy constructions and dissolvable helps—relying on the kind of gentle it’s uncovered to. Ultraviolet (UV) gentle hardens the resin into robust, everlasting shapes, whereas seen gentle produces weaker helps that may be dissolved in particular solvents. The brand new technique eliminates guide post-processing akin to chopping or submitting, accelerating manufacturing and minimizing waste.
In 2020, a analysis staff on the College of Texas at Austin developed a photopolymer resin designed to hurry up high-resolution curing with seen gentle. The panchromatic materials cures below 4 wavelengths—violet, blue, inexperienced, and purple—and consists of a monomer, a photoredox catalyst, two co-initiators, and an opaquing agent. The researchers famous that the resin could be mixed with numerous components, together with organic compounds, enabling purposes in tissue engineering and medical gadget fabrication.
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Picture featured reveals the layer system of the “invisible” QR-code. Picture through TU Wien.
